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Ni2+–Fe3+ cyanometallate structures covalently embedded in silica: Influence of the blocking ligand at Ni2+
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| dc.contributor.author | FELBERMAIR, Elisabeth | |
| dc.contributor.author | AKBARZADEH, Johanna | |
| dc.contributor.author | PETERLIK, Herwig | |
| dc.contributor.author | SIDORENKO, Andrey | |
| dc.contributor.author | PASCHEN, Silke | |
| dc.contributor.author | SCHUBERT, Ulrich | |
| dc.date.accessioned | 2020-12-15T08:15:32Z | |
| dc.date.available | 2020-12-15T08:15:32Z | |
| dc.date.issued | 2019 | |
| dc.identifier.citation | FELBERMAIR, Elisabeth, AKBARZADEH, Johanna, PETERLIK, Herwig et al. Ni2+–Fe3+ cyanometallate structures covalently embedded in silica: Influence of the blocking ligand at Ni2+. In: Inorganica Chimica Acta, 2019, V. 487, pp. 456-464. ISSN 0020-1693. | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.ica.2018.12.019 | |
| dc.identifier.uri | http://repository.utm.md/handle/5014/12105 | |
| dc.description | Access full text - https://doi.org/10.1016/j.ica.2018.12.019 | en_US |
| dc.description.abstract | Ni(II)/Fe(III) cyanometallate structures with Si(OR)3-substituted bis(2-aminoethyl)-1,3-propanediamine or 1,4,8,11-tetraazacyclotetradecane (cyclam) blocking ligands at Ni(II) were prepared and embedded in SiO2 by means of sol-gel processing with Si(OEt)4. The cyanometallates were microcrystalline before sol-gel-processing, and a double-chain structure is proposed for the silyl-substituted [Ni(tetramine)]3[Fe(CN)6]2 derivatives. The 3D arrangement is lost during sol-gel processing, although Fe(III)CNNi(II) structures are retained in the gels, as proven by FTIR and SWAXS studies. The obtained gels show paramagnetic behavior. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elservier | en_US |
| dc.rights | Attribution-NonCommercial-NoDerivs 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/us/ | * |
| dc.subject | sol-gel materials | en_US |
| dc.subject | cyanometallates | en_US |
| dc.subject | silica | en_US |
| dc.subject | small-angle scattering | en_US |
| dc.subject | scattering | en_US |
| dc.title | Ni2+–Fe3+ cyanometallate structures covalently embedded in silica: Influence of the blocking ligand at Ni2+ | en_US |
| dc.type | Article | en_US |
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